Battery research is focusing heavily on lithium chemistries, so much so that one could presume that all portable devices will be powered with lithium-ion batteries in the future. In many ways, lithium-ion is superior to nickel and lead-based chemistries and the applications for lithium-ion batteries are growing as a result.
Lithium-ion has not yet fully matured and is being improved continuously. New metal and chemical combinations are being tried every six months to increase energy density and prolong service life. The improvements in longevity after each change will not be known for a few years.
A lithium-ion battery provides 300-500 discharge/charge cycles. The battery prefers a partial rather than a full discharge. Frequent full discharges should be avoided when possible. Instead, charge the battery more often or use a larger battery. There is no concern of memory when applying unscheduled charges.
Although lithium-ion is memory-free in terms of performance deterioration, batteries with fuel gauges exhibit what engineers refer to as "digital memory". Here is the reason: Short discharges with subsequent recharges do not provide the periodic calibration needed to synchronize the fuel gauge with the battery's state-of-charge. A deliberate full discharge and recharge every 30 charges corrects this problem. Letting the battery run down to the cut-off point in the equipment will do this. If ignored, the fuel gauge will become increasingly less accurate. (Read more in 'Choosing the right battery for portable computing', Part Two.)
Aging of lithium-ion is an issue that is often ignored. A lithium-ion battery in use typically lasts between 2-3 years. The capacity loss manifests itself in increased internal resistance caused by oxidation. Eventually, the cell resistance reaches a point where the pack can no longer deliver the stored energy although the battery may still have ample charge. For this reason, an aged battery can be kept longer in applications that draw low current as opposed to a function that demands heavy loads. Increasing internal resistance with cycle life and age is typical for cobalt-based lithium-ion, a system that is used for cell phones, cameras and laptops because of high energy density. The lower energy dense manganese-based lithium-ion, also known as spinel, maintains the internal resistance through its life but loses capacity due to chemical decompositions. Spinel is primarily used for power tools.
The speed by which lithium-ion ages is governed by temperature and state-of-charge. Figure 1 illustrates the capacity loss as a function of these two parameters.
Lithium-ion has not yet fully matured and is being improved continuously. New metal and chemical combinations are being tried every six months to increase energy density and prolong service life. The improvements in longevity after each change will not be known for a few years.
A lithium-ion battery provides 300-500 discharge/charge cycles. The battery prefers a partial rather than a full discharge. Frequent full discharges should be avoided when possible. Instead, charge the battery more often or use a larger battery. There is no concern of memory when applying unscheduled charges.
Although lithium-ion is memory-free in terms of performance deterioration, batteries with fuel gauges exhibit what engineers refer to as "digital memory". Here is the reason: Short discharges with subsequent recharges do not provide the periodic calibration needed to synchronize the fuel gauge with the battery's state-of-charge. A deliberate full discharge and recharge every 30 charges corrects this problem. Letting the battery run down to the cut-off point in the equipment will do this. If ignored, the fuel gauge will become increasingly less accurate. (Read more in 'Choosing the right battery for portable computing', Part Two.)
Aging of lithium-ion is an issue that is often ignored. A lithium-ion battery in use typically lasts between 2-3 years. The capacity loss manifests itself in increased internal resistance caused by oxidation. Eventually, the cell resistance reaches a point where the pack can no longer deliver the stored energy although the battery may still have ample charge. For this reason, an aged battery can be kept longer in applications that draw low current as opposed to a function that demands heavy loads. Increasing internal resistance with cycle life and age is typical for cobalt-based lithium-ion, a system that is used for cell phones, cameras and laptops because of high energy density. The lower energy dense manganese-based lithium-ion, also known as spinel, maintains the internal resistance through its life but loses capacity due to chemical decompositions. Spinel is primarily used for power tools.
The speed by which lithium-ion ages is governed by temperature and state-of-charge. Figure 1 illustrates the capacity loss as a function of these two parameters.
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Figure 1: Permanent capacity loss of lithium-ion as a function of temperature and charge level.
High charge levels and elevated temperatures hasten permanent capacity loss. Improvements in chemistry have increased the storage performance of lithium-ion batteries.
The mentioning of limited service life on lithium-ion has caused concern in the battery industry and I will need to add some clarifications. Let me explain:
If someone asks how long we humans live, we would soon find out that the longevity varies according to life style and living conditions that exist in different countries. Similar conditions exist with the batteries, lithium-ion in particular. Since BatteryUniversity bases its information on the feedback from users as opposed to scientific information derived from a research lab, longevity results may differ from manufacturer' specifications. Let's briefly look at the various living conditions of the lithium-ion battery.
The worst condition is keeping a fully charged battery at elevated temperatures, which is the case with running laptop batteries. If used on main power, the battery inside a laptop will only last for 12-18 months. I must hasten to explain that the pack does not die suddenly but begins with reduced run-times.
The voltage level to which the cells are charged also plays an important role to longevity. For safety reasons, most lithium-ion cannot exceed 4.20 volts per cell. While a higher voltage boosts capacity, the disadvantage is lower cycle life. Figure 2 shows the cycle life as a function of charge voltage.
Read more this article at http://www.batteryuniversity.com/parttwo-34.htm
